Plastics. Thermogravimetry (TG) of polymers - Determination of the activation energy using the Ozawa-Friedman plot and analysis of the reaction kinetics

Plastics. Thermogravimetry (TG) of polymers - Determination of the activation energy using the Ozawa-Friedman plot and analysis of the reaction kinetics

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1   Scope

This International Standard specifies an analysis method for determining the activation energy using the Ozawa-Friedman plot. It also specifies the preparation of master plots for verification of the reaction kinetics determined by thermogravimetry.
The Ozawa-Friedman plot (logarithm of the rate of mass loss versus the reciprocal of absolute temperature at a given mass loss) is a derivative method that can be applied to data obtained by any mode of temperature change in thermal analysis; e.g. isothermal, constant heating rate, sample-controlled thermal analysis, temperature jump, and repeated temperature scanning.